When you see ammo โcooking off*โ in movies, itโs portrayed as hugely dangerous, like the bullets are firing as if they were in a gun.
But thatโs not actually what happens**. The bullet needs something to โpush againstโ to actually fire, and is greatly accelerated by the barrel of the weapon itโs fired from.
When ammo cooks off, itโs the casing that gains speed (think about why, itโs easy!) and is the part thatโs dangerous, though usually not very dangerous as compared to a bullet fired from a gun.
Anyway, no matter that itโs not all that risky, you still shouldnโt throw ammo in a fire. While a .22 LR brass might not really hurt you, as the cartridge gets bigger so does the M x A of the casing.
*Cooking off generally refers to ammo that fires from being overheated, but here I am using it to refer to any โoutside of the chamberโ firing.
**Source: grew up a a redneck in rural N. Florida where I have seen ammo thrown in a fire, and was in the US Army for five years.